Calcium Hydroxide: A Versatile Alkaline Compound
Calcium hydroxide, commonly known as slaked lime, is a widely used inorganic compound recognized for its strong alkaline properties. It plays a crucial role in construction, water treatment, agriculture, and various chemical processes due to its reactivity and relative safety compared to other strong bases.
Chemical Identity
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Chemical Formula: Ca(OH)₂
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Molecular Weight: 74.09 g/mol
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CAS Number: 1305-62-0
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Common Names: Slaked lime, hydrated lime, caustic lime
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IUPAC Name: Calcium hydroxide
Physical and Chemical Properties
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Appearance: White powder or crystalline solid
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Solubility: Slightly soluble in water (forms limewater)
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pH of Aqueous Solution: ~12.4 (saturated solution)
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Melting Point: Decomposes at ~580°C (to CaO and H₂O)
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Odor: Odorless
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Stability: Stable under normal conditions but reacts with carbon dioxide in the air
When dissolved in water, calcium hydroxide forms a suspension known as limewater, which is often used as a test for carbon dioxide gas (forming a white precipitate of calcium carbonate upon reaction).
Production
Calcium hydroxide is typically produced by the hydration of calcium oxide (quicklime):
CaO + H₂O → Ca(OH)₂ + heat
This exothermic reaction is known as slaking and results in a fine, white powder with many practical uses.
Key Applications
1. Construction Industry
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Used in mortar, plaster, and whitewash
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Plays a key role in the setting of cement and concrete
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Helps improve the plasticity and workability of mixtures
2. Water and Wastewater Treatment
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Serves as a flocculant and pH adjuster in water purification
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Precipitates heavy metals and neutralizes acidic wastewater
3. Agriculture
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Acts as a soil amendment (agricultural lime) to reduce acidity
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Enhances nutrient availability and improves soil structure
4. Chemical Industry
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Intermediate in the production of other calcium compounds
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Used in the manufacture of sodium hydroxide via the causticizing process
5. Food Industry
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Permitted as a food additive (E526) for pH control
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Used in the preparation of corn tortillas (nixtamalization) and other food processing tasks
6. Environmental Uses
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Treats acid mine drainage
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Reduces sulfur dioxide emissions from flue gases in scrubbers
Safety and Handling
Calcium hydroxide is corrosive to skin and eyes in concentrated form but is generally considered safer than many other strong bases.
Hazards:
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Can cause skin irritation, eye damage, and respiratory issues upon prolonged exposure
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Dust may cause irritation to the respiratory tract
Precautions:
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Use protective gear: gloves, goggles, and dust mask
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Avoid inhaling dust or contact with skin and eyes
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Store in dry, well-ventilated areas in tightly sealed containers
Environmental Impact
Though not toxic in small amounts, calcium hydroxide can disrupt aquatic ecosystems if released in large quantities due to its high alkalinity. It reacts readily with atmospheric CO₂ to form calcium carbonate, which is environmentally benign.
Conclusion
Calcium hydroxide is a highly useful and accessible compound that bridges the worlds of construction, agriculture, industry, and environmental management. Its mild yet effective alkalinity, low cost, and broad versatility make it a staple in both traditional and modern applications. However, safe handling is essential to avoid irritation and maintain environmental stewardship.
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